Synthesis and Crystal Structure of a Novel Polymeric Thiocyanato-Bridged Heteronuclear Complex of Copper(II) and Cadmium(II)

The title polymeric complex of Cu(II) and Cd(II) bridged by thiocyanate, Cu(en)₂[Cd(SCN)₃]₂, has been prepared and its structure determined by X-ray diffraction (XRD) methods. The crystal structure reveals that the Cu(II) atom is in an elongated octahedral coordination formed by two SCN^– anions and two en molecules. The Cd(II) atom is in a distorted octahedral coordination formed by six bridging SCN^– anions. Two different bridging thiocyanate anions exist in the complex. Both 1,1--SCN^– and 1,3--SCN^– anion act a role of bridge ligand and link Cu(II), Cd(II) atoms, and adjacent Cd(II). Cd(II) atoms form the three-dimensional (3-D) network polymeric structure. The IR and UV-Vis spectra have also been investigated.     

疏水改性MCM-41对甲草胺缓释性能的影响

采用浸渍法将甲草胺吸附到纯硅MCM-41(M41)介孔材料中, 以六甲基二硅氮烷(HMDS)为表面改性剂, 通过气-固反应对吸附了甲草胺的M41材料(Ach/M41)进行疏水改性, 得到了既具有高载药性又能有效延缓甲草胺释放的缓释体系Ach/TMS-M41. XRD、低温N₂吸附/脱附、FT-IR和TG等分析结果表明, 甲草胺在M41中的吸附量高达0.381 g·g^-1(质量分数为27.6%), 此时M41仍保持原有的孔道结构, 且甲草胺能完全分散于M41孔道中. 分别对Ach/M41和Ach/TMS-M41在水中的缓释性能进行了测试, 甲草胺释放率分别为62%和38.1%, 表明疏水改性对延缓甲草胺释放有较好的效果. 而且, 介孔材料孔壁对甲草胺具有明显的紫外屏蔽保护作用.     

Bounds for the perimeter of an ellipse

In this paper, we present several bounds for the perimeter of an ellipse, which improve some well-known results.     

火焰原子吸收法直接测定铅酸蓄电池用硫酸中铁

建立了火焰原子吸收光谱法直接测定H2SO4中Fe的方法。采用蓄电池用H2SO4样品直接配制标准加入法系列溶液,用火焰原子吸收光谱法直接测定蓄电池用H2SO4中的Fe含量。在选定的仪器测定条件下,采用标准加入法所测得的蓄电池用H2SO4中的Fe含量与国标法所测得的结果相比较无显著性差异,检出限为0.060μg/mL(n=13),1.00μg/mL Fe标准溶液平行测定13次,所得吸光度的相对标准偏差为3.3%(n=13)。本法可应用于H2SO4样品中Fe的测定。     

A field method for integrating the equations of motion of mechanico--electrical coupling dynamical systems

A field method for integrating the equations of motion for mechanico-electrical coupling dynamical systems is studied. Two examples in mechanico-electrical engineering are given to illustrate this method.     

Generalized beam propagation factor of hard-edged circular apertured diffracted Bessel–Gaussian beams

Based on the truncated second-order moments method on the cylindrical coordinate systems and the incomplete gamma function, an analytical expression of the generalized beam propagation factor (M_G² factor) of hard-edged circular apertured diffracted Bessel–Gaussian beams is derived and illustrated numerically. It is shown that the M_G² factor of hard-edged diffracted BGBs mainly depends on the truncation parameter δ and the beam parameters m and η. The results can be reduced to that for the non-truncated Bessel–Gaussian beams case and that for the truncated fundamental Gaussian beams case under certain conditions, respectively. The power fraction is also discussed analytically and numerically.     

Impulsive control and synchronization of the Lorenz systems family

In this paper, impulsive control and synchronization for the newly presented Lorenz systems family are systematically investigated. Some new and more comprehensive criteria for global exponential stability and asymptotical stability of impulsively controlled Lorenz systems family are established with varying impulsive intervals. In particular, several simple and easily verified criteria are derived with equivalent impulsive intervals. An illustrative example is also provided to show the effectiveness and feasibility of the impulsive control method.     

Highly efficient N‐Heterocyclic carbene–palladium complex‐catalyzed multicomponent carbonylative Suzuki reaction: novel practical synthesis of unsymmetric aryl ketones

Highly efficient and chemoselective N‐heterocyclic carbene palladium complexes‐catalyzed multicomponent carbonyltive Suzuki reaction with sodium tetraphenylborate used as phenylating reagent has been demonstrated in this article. Both electron‐rich and electron‐deficient aryl iodides gave unsymmetric aryl ketones in excellent yields. Copyright © 2007 John Wiley & Sons, Ltd.     

Maximal Regular Subsemibands of Singn

We describe maximal regular subsemibands of the singular transformation semigroup Sing_n on the set X_n = {1, 2, . . . n} and obtain their complete classification We show that Sing_n has n(n + 1)/2 maximal regular subsemibands, and formulate the cardinal number of such subsemigroups.